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51.
Robert H. Crabtree 《Journal of organometallic chemistry》2004,689(24):4083-4091
The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also given to σ bond metathesis, surface-bound organometallics and CH activation involving carbene complexes. Closely related reactions of non-alkane substrates such as the Murai reaction are also discussed. 相似文献
52.
A. BOURHIM 《数学年刊B辑(英文版)》2004,25(3):369-382
In this note, the local spectral properties of unilateral operator weighted shifts arestudied. 相似文献
53.
Zhang Shenggui Sun Hao Li Xueliang .Dept.of Appl. Math. Northwestern Polytechnical Univ. Xi''''an China. .Center of Combinatorics Nankai Univ. Tianjin China. 《高校应用数学学报(英文版)》2002,(3)
§ 1 IntroductionAll graphsconsidered in this paperare finite undirected ones withoutloops ormultipleedges.Our terminology and notation are standard exceptas indicated.A good reference forany undefined terms is[1 ] .Let G be a graph with vertex set V( G) and edge set E( G) .The density of G is definedbyd( G) =ε( G)ν( G) ,whereν( G) andε( G) denote| V( G) | and| E( G) | ,respectively.G is said to be balanced iffor each subgraph H of G we have d( H )≤ d( G) ,where V( H ) is assum… 相似文献
54.
A multidimensional version of the first Darboux problem is considered for a model second-order degenerating hyperbolic equation. Using the technique of functional spaces with a negative norm, the correct formulation of this problem in the Sobolev weighted space is proved. 相似文献
55.
Gisella Facchinetti 《Fuzzy Optimization and Decision Making》2002,1(3):313-327
In this paper we present two definitions of possibilistic weighted average of fuzzy numbers, and by them we introduce two different rankings on the set of real fuzzy numbers. The two methods are dependent on several parameters. In the first case, the parameter is constant and the results generalize what Carlsson and Fuller have obtained in (2001). In the second case, the parameter is a function, not fixed a priori by the decision maker, but it depends on the position of the interval on the real axe. In all the two cases we call the parameter degree of risk, which takes into account of a risk-tendency or aversion of the decision maker. 相似文献
56.
We address in this paper the problem of finding an optimal strategy for dealing with bottleneck machines and bottleneck parts in the cell formation process in group technology. Three types of economic decisions are considered: subcontracting, machine duplication and intercell moves. The problem is formulated as a minimum weighted node covering problem in a hypergraph, and we show that it can be solved in polynomial time by finding a maximum weighted stable set in a bipartite graph. We extend this result to cellular manufacturing systems in which the sequence of operations of each part is known in advance. 相似文献
57.
58.
A. V. Sokolov 《Russian Chemical Bulletin》1992,41(10):1750-1755
The concept of the apparent electronegativity of a reaction site has been introduced. This has been used to develop a new scheme for calculating the relative rate constants of addition of radicals with different structures to vinyl monomers. The parameters of the scheme are given for 40 reagents. The results of a comparison of calculated and literature rate constants of addition are presented.Institute of Nonaqueous Solution Chemistry, Russian Academy of Sciences, 150003 Ivanovo. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2238–2245, October, 1992. 相似文献
59.
Xiao‐Hui Liu Yan‐Guo Li Ying Lin Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1272-1281
The reversible addition–fragmentation chain transfer (RAFT) polymerization of acrylonitrile (AN) mediated by 2‐cyanoprop‐2‐yl dithiobenzoate was first applied to synthesize polyacrylonitrile (PAN) with a high molecular weight up to 32,800 and a polydispersity index as low as 1.29. The key to success was ascribed to the optimization of the experimental conditions to increase the fragmentation reaction efficiency of the intermediate radical. In accordance with the atom transfer radical polymerization of AN, ethylene carbonate was also a better solvent candidate for providing higher controlled/living RAFT polymerization behaviors than dimethylformamide and dimethyl sulfoxide. The various experimental parameters, including the temperature, the molar ratio of dithiobenzoate to the initiator, the molar ratio of the monomer to dithiobenzoate, the monomer concentration, and the addition of the comonomer, were varied to improve the control of the molecular weight and polydispersity index. The molecular weights of PANs were validated by gel permeation chromatography along with a universal calibration procedure and intrinsic viscosity measurements. 1H NMR analysis confirmed the high chain‐end functionality of the resultant polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1272–1281, 2007 相似文献
60.
We consider quasi-isometric mappings of domains in multidimensional Euclidean spaces. We establish that a mapping depends continuously in the sense of the topology of Sobolev classes on its metric tensor to within isometry of the space. In the space of metric tensors we take the topology determined by means of almost everywhere convergence. We show that if the metric tensor of a mapping is continuous then the length of the image of a rectifiable curve is determined by the same formula as in the case of mappings with continuous derivatives. (Continuity of the metric tensor of a mapping does not imply continuity of its derivatives.) 相似文献